Fast-charging solid-state batteries

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There are currently great hopes for solid-state batteries. A new concept now allows high charging currents by a “clever” choice of materials.

Solid-state batteries are currently being developed with priority as energy storage for next-generation electric vehicles. But we also believe that solid-state batteries will prevail in other fields of application that require a long service life and safe operation, such as medical technology or integrated components in the smart home area. Because they do not overheat or even explode when damaged, unlike lithium-ion batteries, they would also be a safe alternative for smartphones and other mobile computers.

But the low current is considered one of the biggest hurdles in the development of solid-state batteries. It is the reason why the batteries take a relatively long time to charge. It usually takes about 10 to 12 hours for a solid-state battery to fully charge. The new cell type that Jülich scientists have designed, however, takes less than an hour to recharge.

With the concepts described to date, only very small charge and discharge currents were possible due to problems at the internal solid-state interfaces. This is where the new concept based on a favourable combination of materials comes into play, and it is already patented.

Solid-state batteries with high charging rates

In conventional lithium-ion batteries, a liquid electrolyte is used, which usually contacts the electrodes very well. With their textured surfaces, the electrodes soak up the liquid like a sponge, creating a large contact area. In principle, two solids cannot be joined together seamlessly. The contact resistance between the electrodes and the electrolyte is correspondingly high.

In order to allow the largest possible flow of current across the layer boundaries, the scientists used very similar materials to produce all components. The anode, cathode, and electrolyte were all made from different phosphate compounds to enable charging rates greater than 3C (at a capacity of about 50 mAh/g). This is ten times higher than the values otherwise found in the literature.

The solid electrolyte serves as a stable carrier material to which phosphate electrodes are applied on both sides using the screen printing process. The materials used are reasonably priced and relatively easy to process. Unlike conventional lithium-ion batteries, the new solid-state battery is also largely free of toxic or harmful substances.

In initial tests, the new battery cell was very stable over 500 charge and discharge cycles and retained over 84 percent of its original capacity. But theoretically, a capacity loss of less than 1 percent should even be feasible. The energy density is already very high at around 120 mAh/g, even if it is still slightly below that of today’s lithium-ion batteries.


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Solid-State Batteries (Image: Forschungszentrum Jülich / Regine Panknin)

The patented concept is based on a favourable combination of materials. (Image: Forschungszentrum Jülich / Regine Panknin)